The exploit typically involves crafting a malicious email header, which is then passed to the mail() function. By injecting specific command-line arguments, an attacker can execute arbitrary system commands.
You're referring to a well-known vulnerability in PHP's email form validation.
In 2011, a critical vulnerability was discovered in PHP, which allows an attacker to inject malicious data into the mail() function's parameters. This vulnerability is known as CVE-2011-4341, also referred to as the "PHP Mailer" vulnerability.
The vulnerability you're referring to is likely related to a remote code execution (RCE) vulnerability in PHP, specifically in the mail() function, which is commonly used in contact forms.
Here's an example of an exploit: